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Enantioselective intermolecular iodoacetalization of enol ethers catalyzed by chiral Co(III)-complex-templated Bronsted acids

文献类型: 外文期刊

作者: Li, Na 1 ; Yu, Hao 1 ; Wang, Rui 1 ; Shen, Jia 2 ; Wu, Wen-Qiang 1 ; Liu, Kun 3 ; Sun, Ting-Ting 1 ; Zhang, Zheng-Zhu 3 ; Ya 1 ;

作者机构: 1.Anhui Agr Univ, Dept Appl Chem, Hefei 230036, Anhui, Peoples R China

2.Anhui Acad Agr Sci, Tobacoo Res Inst, Hefei 230031, Anhui, Peoples R China

3.Anhui Agr Univ, State Key Lab Tea Plant Biol & Utilizat, Hefei 230036, Anhui, Peoples R China

关键词: Chiral Co(III) complexes; Bronsted acid; Intermolecular; Iodoacetalization

期刊名称:TETRAHEDRON LETTERS ( 影响因子:2.415; 五年影响因子:2.036 )

ISSN: 0040-4039

年卷期: 2018 年 59 卷 40 期

页码:

收录情况: SCI

摘要: The chiral Co(III)-complex-templated Brensted acids were used as efficient bifunctional phase-transfer catalysts for the asymmetric intermolecular iodoacetalization of enol ethers, such as 3,4-dihydro-2H-pyran, 2,3-dihydrofuran, ethyl vinyl ether with alcohols and NIS, furnishing the 3-iodoacetals in high yield with up to 83:17 er. (C) 2018 Elsevier Ltd. All rights reserved.

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